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  Home >> Inorganic Chemistry Dictionary >> Emission Spectrum - Enol Keto Tautomerism

Emanation
An obsolete name for radon.

Emission spectrum
a spectrum formed by a material which is heated, e.g., a white hot wire, or by excitation from an electric arc or electric discharge, e.g., as seen in gases in a discharge tube. A spectrum can be a continuous line or a band spectrum. It is formed in the visible region or in the infrared or ultra-violet region of e.m. waves. It is produced by extra-nuclear electrons first being excited by energy and being raised to a higher energy level, and then falling back to a lower energy level and emitting energy level and emitting energy in the form of e.m. waves.

Emulsion breaking
In an emulsion, the combined sedimentation and coalescence of emulsified drops of the dispersed phase so that they will settle out of the carrier liquid; can be accomplished mechanically (in settlers, cyclones, or centrifuges) with or without the aid of the droplets.

Enantiotropy
Refers to the existence of different stable allotropes of an element at different temperatures; sulphur, for example, exhibits enantiotropy. The phase diagram for an onantiotropic element is having a point at which all the allotropes can coexist in a stable equilibrium. At temperatures above or below this point, one of the allotropes will be more stable than the others(s).

Energy bands
Refers to continuous bands of energy arising from a series of close energy levels occurring mainly in metals where the valency electrons from bonds with an increased number of quantized energy levels.

Enol-Keto tautomerism
The tautomeric migration of a hydrogen atom from an adjacent carbon atom to a carbonyl group of a keto-compound to produce the end form of the compound, the reverse process of hydrogen atom migration also occurs.
Epoxy resins
Polyethers obtained by condensation of epichlorophydrin with polyols like bisphenol A, or by epoxidation of Diels-Alder adducts with peroxy compounds. These are used as adhesives protective coatings, etc.

Equivalent electrons
Electron in an atom which have the same principal and orbital quantum numbers, but not necessarily the same magnetic orbital and magnetic spin quantum numbers.

Erbium
Symbol Er, a soft silvery metallic element belonging to the lanthanides; a. n. 68; r.a.m. 167.26; r.d. 9.066 (200c); m.p. 15290 C; b.p. 28680 C. It occurs in apalite, gadolinite, and xenotine from certain sources. There are six natural isotopes, which are stable, and twelve artificial isotopes are known. It has been used in alloys for nuclear technology it is a neutron absorber; it is being investigated for other potential uses.

Essential amino acid
Refers to an amino acid that an organism is unable to synthesize in sufficient quantities. It must therefore be present in the diet. In man, the essential amino acids are arginine, Histidine, lysine, threonine, methionine, isoleucine, leucine, valine, phenylanine, and tryptophan.

Ethylene oxide
1, 2-epoxyethane, oxirane CH2. CH2O. Colourless gas with a sweet odour which is somewhat lachrymatory; b.p. 10.50C.

Emulsification
The process of dispersing one liquid in a second immiscible liquid; the largest group of emulsifying agents are soaps, detergents, and other compounds, whose basic structure is a paraffin chain terminating in a polar group.

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