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  Home >> Chemistry Dictionary >>Asphaltic Bitumen - Atactic Polymers

Asphalt.
A black semi-solid stickly substance which is mixture of bitumen with mineral matter, e.g. rock asphalt or to a mechanical mixture of bitumen, aggregate, sand and filler, i.e. hot rolled asphalt.

Asphalt emulsions.
See bitumen emlusions.

Asphaltic bitumen.
A black or brown viscous liquid or solid, consisting hydrocarbons and their derivatives, obtained from crude oil as a distillation residue or from natural sources or combined with mineral matter in natural asphalt. It posses good waterproofing and adhesion properties and is used largely for road construction, waterproof or protective coating and electrical insulation.

Asphalties.
Naturally occurring hard bitumens of high purity containing only 1-2% of mineral matter.

Aspirin, o-O-Acetylslicylic Acid.
C9H8O4. Colourless crystals, m.p. 135-138°C. Manufactured by the action of ethanoic anhydride on salicylic acid. It is widely used in tablet form as the acid or a salt as an analgesic and antipyretic.

           

Associated liquids.
Liquids which are composed wholly or partly of loosely combined aggregates of two more molecules, rather than, as in the case of normal unassociated liquids, single molecules.

Association.
A term applied to the combination of molecules of one substance with another to form more complex molecules. Substances showing this effect are said to be associated.

Astatine.
At At. no. 85. A radioactive halogen-formed in natural radioactive decay series but studied on 211At formed by a-bombardment of 200Bi. Rather little is known of the chemistry of the element, electric configuration 6s26p5. Oxidation states established include-1 (At-formed by reduction with SO2 or Zn. AgAt insoluble), +1 ([AtO]-) formed form At-, water and Br2 or Fe3+ also [Atpy2]+) and +5 ([AtO3]- from [AtO]- and hypochlorite or [S2O8]2-).

Asymmetric atom.
Refers to an atom of polyvalent element like carbon, nitrogen bearing dissimilar atomic groups or atoms of other elements as substituents.

At.
Astatine.

Atactic polymer.
If in crystalline polymers it is considered that the carbon atom in any chain lie in the same plane with a regular arrangement of the substituents the structure may be either isotactic or syntactic. If there is no stereospecificity of the substituents with respect to the carbon atoms then the polymer is said to be atactic.

Athabasca tar sands.
Naturally occurring mixture of bitumen and sand found in Northern Alberta.

Atmolysis.
Refers to separation of a mixture of gases by means of their different rates of diffusion. Usually separation gets effected by allowing the gases to diffuse through the walls of a porons partition or membrane.

Atmosphere.
A unit of pressure equal to 101325 pascals. This is equal to 760.0 mm Hg. The actual atmospheric pressure fluctuates around this value. The unit is usually used for expressing pressures well in excess of standard atmospheric pressure, e.g. in high pressure chemical process.

Atom.
The smallest part of an element which can exist as a stable entity.

Atomic heat.
The number of Joules of heat required to raise the temperature of one male of atoms of an element through 1 Kelvin.

Atomicity.
The number of atoms in a molecule of an element or a compound e.g. the atomicity of hydrogen is 2(H2) the atomicity of Sulphur dioxide is 3(SO2) the atomicity of helium is 1 (He).

Atomic mass (amu)
The mass of an individual atom is very small. Mass of hydrogen and oxygen are 1.673×10-24 and 26.558×10-24g, respectively. To express masses of atoms in a convenient way, the unit called atomic mass unit (amu) is introduced. Hydrogen being the lightest element was taken as standard and its atomic mass was fixed equal to unity. In 1961, a refinement was made and the unit was changed. The present unit is based on the C-12 isotope which is nearly 12 times as heavy as the hydrogen atom. The atomic mass unit is exactly 1/12 the mass of one 12-C atom.

Atomic nucleus.
A part of an atom-having most of its mass, positively charged. Consists of protons and neutrons. The positive charge of a nucleus is equal to the number of protons in contains, Z.

Atomic number (z).
The number of protons in the nucleus of one of its atom. Atomic number = Mass number – Number of neutrons.

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